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In more oxidized sediments or waters, oxides may be a significant sink for Co [3, 17].
In oxidized sediments, dissolved ammonium can also be removed via nitrification.
Although there is little difference in XAS spectra for the reduced and oxidized sediments, we cannot rule out the possibility that chromium and lead desorb and are taken up by the iron (oxy)hydroxides that forms as pyrite oxidizes.
We also discuss the geochemical processes responsible for the transfer of these metals from reduced contaminated estuarine sediments to oxygen-rich seawater by comparing in situ geochemistry with that of the oxidized sediments.
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Light patches are oxidized sediment surrounding older burrows.
These numbers are based on comparison of EXAFS analyses of the reduced and oxidized sediment, and on the net amount of metal dissolved during the experiment (Fig. 6 and 7).
These values fall within the range of, but slightly lower than, those reported by Stollenwerk et al. [ 19] when studying As adsorption oxidized aquifer sediments.
A previous study [27] also showed that R. mangle can oxidize the sediment rhizosphere and thereby contribute to the reduction of hydrogen sulfide in the sediment.
The fate of these metals during dredging was evaluated by comparing in situ geochemistry with that of sediments oxidized by seawater in laboratory experiments.
However, burrow networks built by macroinfauna create a complex 3-dimensional patchwork of relatively more oxidized or reduced sediment compartments.
Methane efflux measurements at other clam habitats indicated that the uprising methane is completely oxidized in the sediment (Sommer et al., 2006; Pop Ristova et al., 2012).
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