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Analysis of the H2O2-mediated film dissolution processes via open circuit potentiometry, alpha counting and SEM/EDX imaging has shown that in near-neutral solutions of pH 6.1 and at [H2O2] ⩽ 100 μmol dm−3 the electrodeposited uranium oxide layer is freely dissolving, the associated rate of film dissolution being significantly increased over leaching of similar films in pH 6.1 peroxide-free water.
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The residue left over from leaching the original mineral concentrate contains rhodium, iridium, ruthenium, and osmium.
This discrepancy is a further support for our conclusion that the bicarbonate buffer oxidizes the magnetite over time by leaching Fe2+ from the solid phase.
Results showed that the Cu-Au tailings tested in this study were relatively stable after natural weathering, with little resilience of peak salinity, stable pH and low levels of metals in leachate against the six cycles of leaching over 20 weeks.
Figure 3 Dynamic of As in the first 50-ml leachate over six cycles of leaching.
Figure 5 Dynamic of Fe in the first 50-ml leachate over six cycles of leaching.
Figure 4 Dynamic of dissolved organic C in the first 50-ml leachate over six cycles of leaching.
Leachate pH of the EHM tailings kept relatively stable after 20-week leaching (Figures 1 and 2). Figure 1 Dynamic of electrical conductivity (EC) in the leachate over six cycles of leaching.
Over 99% of indium in leaching solution was finally enriched by Zn substitution or sulfide precipitation.
We show that these electrodes are both electrochemically efficient and stable to leaching or degradation over millions of turnovers.
Similarly drug free gels were also subjected to permeation studies to rule out any interference due to leaching from tissues over a period of time.
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