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This means that Nb impedes the outward diffusion of Al.
Microstructural observations suggested that yttrium also slows Ni outward diffusion.
The appearance of the monoclinic ZrO2 phase (Fig. 1) can be explained by outward diffusion of Cu which stimulates outward diffusion of Y from such grains [32].
This suggests an outward diffusion of the Ni species toward oxygen ions.
In this specific microstructure only the columnar GB contribute to the outward diffusion of Cr.
During their oxidation, an outermost TiO2 layer was formed by outward diffusion of Ti ions, and the outer Al2O3 layer was formed by outward diffusion of Al ions.
These defects enhance the diffusion of elements and may even form additional GBs which increase the outward diffusion of Cr.
This was facilitated to a certain extent by the concurrent outward diffusion of H2 bubbles as the Si was etched.
This manipulation was used to prevent Ge outward diffusion in Ge-doped samples upon thermal treatment [22].
This transformation of Ge distribution can be caused by the outward diffusion of Ge during annealing (Fig. 4b).
Microstructural evaluation indicated that the spinel layers inhibited outward diffusion of chromium.
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