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The triarylimidazoles (TAIs) constitute a promising class of organic electron transfer redox mediators that have been used to achieve indirect electrochemical C-H bonds activation and functionalization.
A scheme of a glucose dehydrogenase-based bioelectrocatalytical system where ferricyanide is converted to ferrocyanide in the presence of highly reactive organic electron transfer compounds is investigated digitally.
Glucose dehydrogenase (GDH) is highly reactive towards organic electron acceptors compared to the low reactivity of GDH with inorganic electron acceptors.
In this review, the authors explore organic electron donors and acceptors that have been developed in the past 3 years (2013 2016) and have led to high-efficiency photovoltaic devices.
Composite catalysts for photocatalytic hydrogen (H2) evolution were prepared by loading an organic electron donor acceptor linked dyad [2-phenyl-4- 1-naphthyl)quinolinium ion, QuPh+–NA] as an organic photosensitizer and Pt or Cu particles as H2-evolution catalysts on alumina-silica.
One possible route is the introduction of organic electron acceptors into a conjugated polymer matrix.
Similar(29)
The synthesis of organic electron-transport materials (ETMs) for organic light-emitting diodes (OLEDs) has been intensely pursued.
Shewanellae are capable of using a vast respiratory network to reduce various organic and non-organic electron acceptors[1].
Unlike conventional inorganic metals in which electrons zip through a crystalline lattice, in organics electrons must hop from one molecule to another, like pails of water being passed by a bucket brigade.
In addition to providing in-depth understanding of this phenomenon, our study offers design guidelines for improved organic organic heterojunctions, hole- or electron-blocking layers and reduced barriers for charge-carrier injection in organic electronic devices.
We chose an organic terminal electron acceptor to prevent the formation of metal precipitates on the cell surface (likely to form with either Fe3+- or Mn4+-containing electron acceptors) which would preclude the study of true cell-surface, mineral-surface interactions.
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