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On the other hand, the monomers were chemically polymerized with Bisphenol-A to retain the metal moiety in the backbone of the polymer, affording the possibility of strong electronic interactions between the organic bridge and metal group in this arrangement.
These modified AuNPs were again self-assembled with Au@Ag core shell bimetallic nanoparticles via the SH groups to produce an organic bridge between Au and Au@Ag metallic nanoparticles.
The effects of: i) the type of organic bridge; ii) the presence of nitrogen atoms; iii) the use of an acid catalyst prior to carbonization; and iv) pore size were investigated.
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The nanostructured bridged organoniobosilicates have been synthesized by the acid catalyzed hydrolysis and condensation of bridged silsesquioxane precursors containing two different organic bridging groups ((C2H5O 3Si R Si OC2H5 3, R: ethylene or octylene) in the presence of nonionic template P123.
In this precursor molecule two Si atoms are bound to one organic bridging group (T site) while one Si is bound to two organic bridging groups (D site).
They are a class of porous polymeric material consisting of metal ions linked together by organic bridging ligands.
In this paper, we provide an overview of recent development of hybrid silica membranes that contain organic bridges.
A metal organic framework (MOF) represents a new class of hybrid material built from metal ions with well-defined coordination geometry and organic bridging ligands.
The result shows that the structures and properties of the metal organic materials can be finely tuned by the substituent on the organic bridging ligands.
As a newly emerging fascinating nanomaterial, infinite coordination polymers (ICPs) constructed by metal ions and organic bridging ligands, have spurred growing interests.
The presence of organic bridging groups inside the frameworks may be a potential advantage over purely inorganic systems because of the greater variability of pore surface properties that can be achieved [4].
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