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So, the first order peak was selected for label-free detection.
At higher temperatures a gradual disappearance of this first order peak was interpreted as a gradual dissolution of the micro domain structure.
On heating, the loss of long range order was observed as a sudden broadening of the line profiles of the first order peak.
It is a well-documented phenomenon that the value of S 0 is always smaller than the H-R parameter measured between higher order satellite peaks [21] due to the fact that whilst all recombining excitons contribute to the zero order peak, only those that are deeply confined contribute meaningfully to the higher order satellites.
A close inspection of their XRD data show that the full width at half maximum (FWHM) of the second order peak of (110) (i.e., the peak (211) shown in Fig. 2 of their work) has a lower value of FWHM as compared to the (110) peak, which clearly indicates the nonhomogenity nature of their powders.
After baseline correction (Fig 6D), the measurement of spacing suggests that this arrangement is lamellar (2nd order peak spacing close to d/2).
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The fast Fourier transform (FFT) of these images shows that the cleaned image only captures the signal from a few lower order peaks while information from several higher order peaks are lost.
This unusual behavior of the higher order peaks was explained by the lamellar insertion model of Hama and Tashiro.
In the crystalline state of the neat LEI, the first and higher order scattering peaks were clearly observed, in which the intensity of the higher order peaks was considerably strong.
The presence of higher order peaks is indicative of high ordering in the thin films.
The annealed sample clearly shows presence of primary and higher order peaks indicating a long-range order, whereas the profile of the sheared and quenched sample shows absence of higher order reflections indicating that the long-range order associated with the BCC lattice is lost due to shear even at very low shear rates.
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Justyna Jupowicz-Kozak
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