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Accordingly, our results (the position of Ag 3d signal as well as the splitting of spin orbit component of almost 6.0 eV) are consistent with silver compounds and metallic silver which provide unambiguous information on the identity of the Ag oxidation state.
XPS results revealed that Ti2p spin-orbit components of Fe3 +:TiO2 composite films are shifted towards higher binding energy, with respect to TiO2 films, suggesting that some of the Fe3 + ions are incorporated into TiO2 lattice.
By curve-fitting analysis of Au4f spectra of hybrid (1), two pairs of spin-orbit components appear.
The curve-fitting analysis of the two spin-orbit components of the Au4f signal is shown in Figure 10.
Considering for example sample A1, two contributions were found by curve-fitting analysis of the two spin-orbit components of the Au4f signal (Figure 7).
Au4f spectra of hybrid (1) exposed to NO x gas, exhibit two pairs of spin-orbit components, in analogy to the precursor.
The spin-orbit components (Zn 2p3/2 and Zn 2p1/2) are separated by a binding energy interval of approximately 23.0 eV [49, 51 53].
However, the peak at 294.6 eV, not resolved by curve-fitting in the two spin-orbit components, can either be ascribed to K2p for non-stoichiometric oxides or misinterpreted by confusion with energy losses in the C1s background region.
Also in this case, Au4f signal is structured and two pairs of spin-orbit components are founded; the first Au4f7/2 component at BE = 83.53 eV is associated with metallic gold atoms, while the second Au4f7/2 component at higher BE values (85.35 eV) is assigned to the Au atoms that are covalently bonded to sulfur terminal groups of benzylthiol.
Averages of those field components over one orbit are easily related to the Gauss coefficients.
And contamination from umodelled magnetospheric sources, most likely originating from asymmetries in the ring current, have been observed in CHAMP data by Balasis et al. (2004) in their degree 1 magnetospheric models and by Kunagu et al. (2013) in mean magnetic field components calculated each orbit using the same 12 hour local-time window used above.
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