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The optically pure monomers derived from 2 and 3 afford optically active polymers whose optical activities are independent of cis content and molecular weight, indicating the absence of a cooperative effect between chiral centres along the chain.
This is the first report about both left- and right-handed chiral nanostructures with unique optical activities.
All these results indicated that the nonlinear optical activities could be enhanced by introducing suitable additional heteroatoms into donor moiety.
The colors and optical activities of these nanofibers can be maintained on an indium-tin oxide (ITO) coated electrode with a dedoping/redoping treatment.
The optical activities of the helical PANI nanofibers reversibly varied with different oxidized forms, which were easily controlled by the different potentials applied to the nanofibers.
We report on the synthesis and characterization of new crosslinked polymeric matrices functionalized with heterocycle-based dyes, showing enhanced second and third order nonlinear optical activities.
Similar(47)
A compound that displays this ability is called optically active (see optical activity).
In this type of reactions there is a inversion of optical activity from R to S or vice versa in optically active compounds.
The aromatics are not optically active themselves in the near UV but, when held rigidly in an asymmetric environment, exhibit optical activity [35].
Cumulative symmetry is responsible for optical activity.
Optical activity accordingly is likely to be a feature of life on any planet.
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