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The opposite configurations allow enantiomers to be discriminated by their enantiospecific interactions with another chiral molecule in membranes.
Figure 5 shows the 3-dimensional structure of meso-tartaric acid having two constitutionally identical, but stereochemically different, chiral centers (opposite configurations).
In this research, we fabricated chiral surfaces by assembling natural chiral amino acids-cysteine of opposite configurations (D- and L-) onto gold surfaces, respectively, and investigated the adhesion of the L929 fibroblast on them.
The HTSC formation of substituted PLA with opposite configurations reported in the present study will provide a versatile way to prepare poly 2-hydroxyalkanoic acid)-based biodegradable materials having a wide variety of poly 2-hydroxyalkanoicd biodegracid -based
The SO as the functional unit for enantioselectivity contains a β-aminocyclohexanesulfonic acid moiety and is readily accessible via straightforward synthesis in both enantiomeric forms yielding chiral stationary phases (CSPs) with opposite configurations, CSPs 1 and 2, and reversed elution orders.
The crystallization behavior of the stereoblock copolymer of substituted and non-substituted poly(lactide)s, i.e., poly d-2-hydroxybutyrate) and poly d-2-hydroxybutyrateaving the opoly d-2-hydroxybutyrateP(D-2HB)-b-PLLandand the reference block copoly l-lactidey(d-2-hydroxybutyrate) and poly l-lactide) chains withavingidentheal coppositetions [P(D-2HB)-b-PDLA] was investigated.
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The opposite configuration is called a tricycle gear, with a single nose wheel and two main wheels farther back.
(Also welcome are sugars of the opposite configuration).
Of them, compounds 84 and 85 are diastereoisomers with opposite configuration at C-25.
Compounds 76 and 77, isolated from the root of S. officinalis, are the diastereoisomers with opposite configuration at C-5 [29].
The opposite configuration causes a main vortex to be succeeded by a wake where vortex structures are not clearly defined.
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