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This surface area loss was found to be relatively insensitive to electrode operating potential.
The amperometric measurement was optimized at +450 mV operating potential and 30 mM ferricyanide in a 0.1 M phosphate buffer (pH 7.0) at 26 °C.
The effects of operating potential, inlet gas composition, inlet gas velocity, electrode permeability and electrode porosity on the coupled transport and electrochemical reaction as well as the electric output of the SOFC were invested in detail.
It has been shown that poly N-methylaniline) modified electrode can be used as an ampoly N-methylaniline sensor, operating in slightly acidic or pH-neutral buffer solutions at a controlled potential of 0.1–0.5 V versus Ag/AgCl, and the dependencies of current response on ascorbate concentration, the thickness of a polymodifiedr, and opelectrodeotential have been analyzed.
The amperometric response of the AuNP-FLG based electrode achieved an excellent electrocatalytic activity towards glucose oxidation with a wide linear detection range of 6 μmM28.5 mM, low detection limit of 1 μM and a sensitivity of 0.195 μA mM−1 cm−2 at operating potential of 0.0 V.
In addition, symmetric flexible solid state supercapacitor (FSS-SCs) device fabricated using β-NiS thin films and polyvinyl alcohol-lithium perchlorate (PVA LiClO4) as a polymer gel electrolyte, shows acceptable Cs of 55.83 Fg− 1 at scan rate of 10 mV s− 1 within operating potential window of 1.2 V.
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Therefrom, we theoretically predicted the optimum range of operating potentials, yielding design guidelines for catalytic surfaces.
The analysis is conducted for operating potentials of 0.7 and 0.6 V and a range of current densities.
The anode and cathode half-cells provided operating potentials of −0.44 and 0.48 V, respectively (vs. Ag/AgCl).
When [EMIm][BF4] electrolyte is coupled with electrodes containing PTFE binder, operating potentials as wide as 3.8 V can be utilised.
Single cells using these catalysts showed I E performance superior to that for the Pt/CB at operating potentials above 0.4 V.
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