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The reaction mechanism that we speculated was the oxidized ring opening reaction and hydrolysis.
This leads to a fast ring opening reaction of the epoxide.
Epoxide ring opening reaction is a route that explains the chemical modification of glycidyl methacrylate (GMA) polymers with nucleophilic reagent containing hydroxyl, carboxyl or amine groups.
The reaction was designed in dichloromethane excluding ethereal solvents such as THF because, in the presence of TiCl4, O-heterocycle ring opening reaction occurs [41, 42].
Linear-carbon-chain molecules have been shown to form by the atomic carbon addition-ring opening reaction (ACAROR) mechanism.
The grafting principle used to stabilize the poly(GMA-co-SBMA) on the target surfaces is based the base-induced ring opening reaction between epoxied and hydroxyl groups.
Similar(31)
The thermally stable derivative 234 undergoes photochemically reversible ring-opening reaction to give 235, which liberates ethylene via reverse Diels Alder reaction (Scheme 106).
Main disadvantage of using potassium salt is the ring-opening reaction of coordinated THF.
Table 3 lists the hydrogenation and selective ring-opening reaction results of THN at different LHSVs.
It was concluded that the high temperature could promote the THN ring-opening reaction.
PHEA polyhydroxyethyl aspartamide -mPEG-C16-ED waspartamide -mPEG-C16-EDG-C16 viaspartamide -mPEG-C16-EDwith ethylenediaspartamide -mPEG-C16-ED
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