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Laboratory experiments demonstrated that the sampling-rate calibration method was practical and could be used for the quantification of on-site sampling.
For example, when slaughter pigs are the target population, sampling the pigs on the slaughter line may be an alternative to on-site sampling at a list of farms.
The output from analysis predicts trends in species distribution that are consistent with independent on-site sampling for each species and therefore should prove useful in gauging the extent of resource availability.
The sorbent can be easily dispersed in aqueous solutions for extraction and no additional stirring or shaking was necessary to facilitate the dispersion, which may bring operational convenience especially for on-site sampling and extraction.
In these approaches, a miniature battery-operated electric stirrer was employed to provide agitation of sample solutions instead of the commonly used large size magnetic stirrer powered by alternating current in conventional SBSE process, which could extend the SBSE technique from the conventional off-site analysis to the on-site sampling.
The accuracy of the developed method was evaluated by recovery test and the recoveries for the spiked sample were found to be in the range of 87.1 122.8% for off-site CF-SBSE, 88.8 114.3% for on-site sampling, and 87.7 123.6% for off-site SBSE, respectively.
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In this work, a portable prototype of tip microextraction device (TMD) was designed and developed for on-site sample pretreatment.
The adjoining FSVC clinic features small animal exam rooms, a surgical suite and an in-house laboratory for quick, on-site sample analysis.
On-site sample preparation is highly desired because it avoids the transportation of large-volume samples and ensures the accuracy of the analytical results.
The overall approach of on-site sample concentration, on-filter amplification, and live/dead differentiation may be extended to other organisms where analytical sensitivity and speed are equally important.
To evaluate the practicability of the developed device, the TMD was used to on-site sample preparation of waters and combined with high-performance liquid chromatography with diode array detection to measure trace estrogens in water samples.
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