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In the presence of OH, ethanol reacts with OH to form the DMPO-CH(CH3 OH adduct (C).
The heterolytic path which involves the oxidation of CO by OH to form CO2+H+(aq)+e− is more favorable than the homolytic path.
DFT simulation results indicate that BDD edge sites (=CH2) can be converted to COOH functional groups, which are further oxidized via reactions with OH to form H2CO3 aq). with an activation energy of 58.9 kJ mol−1.
However, if little oxygen is present, those intermediate species easily recombine with each other or are oxidized by OH to form unwanted by-products, such as HCOOH and HCHO.
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However, sodium sulfite should be avoided since it reacted with DMPO-OH to form DMPO-SO3.
We report here the development of a simple biocompatible, bioluminescent method for measuring DAO activity based on the highly selective condensation of d-Cys with 6-hydroxy-2-cyanobenzothiazole (CBT-OH) to form d-luciferin.
Because d-luciferin is a common substrate used in bioluminescence studies, we chose to use d-Cys as a substrate in our investigations because it can be metabolized by DAO but can also react with 6-hydroxy-2-cyanobenzothiazole (CBT-OH) to form d-luciferin.
In this process, TBA is known as the OH radical scavenger which could react with the OH radicals to form the inert intermediate that leading to the termination of the PEC degradation.
Benzene is subsequently attacked by OH radicals to form phenol which can submit an oxidative opening of the aromatic ring leading to low molecular weight aliphatic carboxylic acids, such as formic and acetic acid.
The thermal change of indium 2-ethylhexanoate monohydroxide, In(OH)(O2CCH(CH2CH3)(CH2)3CH3)2, to form indium oxide, In2O3, thin film was investigated by TG DTA MS in a He 20%O2 atmosphere with a minute amount of specimen (∼0.1 mg) in order to clarify the formation process of the indium-tin-oxide transparent conducting films (thickness, ∼240 nm).
Depending on the position of the extracted H atom on the ring or on the side chain, the oxidation of ECH is mainly initiated by H-abstraction with OH radical to form cyclic C8H15 radicals having six isomers (R1 R6) at low (500−900 K) and intermediate (900−1100 K) temperature and in this study we focus on the kinetics of the reactions starting from these isomers.
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