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It can be seen that the higher rigidity of the polymer (longer alkyl chain of side group), the higher σdc.
It has been found that the longer the chain length of side group and the smaller the ring size could result in much better PL.
Cyclic voltammetry, UV vis spectroscopy and DFT calculations are used to establish that the porphyrin LUMO, HOMO and bandgap are independent of side group.
This study is the first of its kind to systematically investigate the effect of side group structure on the compressive strength of novel biodegradable polyphosphazene based polymers as potential materials for tissue regeneration.
The αc- and αa-relaxations are associated with the molecular motions in the crystalline regions and micro-Brownian motion in the amorphous regions of the main polymer chain, respectively, whereas the β-relaxation is attributed to the rotation of side group dipoles or to the local oscillations of the frozen main polymer chain.
The phosphopeptide-capturing compound was composed of a soluble dendrimer, to which two types of side group were bound (Fig. 6).
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The various forms differ in minor modifications of side groups attached to the pyrrole groups.
"We envisioned we could attach a lot of side groups to it easily," Dr. Katz said.
Hence, the elasticity of the polymer chain can be different depending on the properties of side groups and solvents.
However, both in-plane thermal expansivity and thermal stability were relatively degraded by the incorporation of side groups.
Furthermore, refractive indices, dielectric constants, and their anisotropies were all reduced by the incorporation of side groups.
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