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The combination of pyrolysis with in situ methylation using TMAH to depolymerize the fragments through methylation of methyl esters from carboxylic acids and methyl ethers from alcohols/phenols is an easy and efficient method for the characterization of lignin-derived compounds.
Air exposure enhances the degradation of methyl esters.
The 1H-NMR analysis confirms the formation of methyl esters.
The upper layer consisted of methyl esters (biodiesel) and unconverted triglycerides.
Low values of free glycerin reveal that high concentrations of methyl esters have been produced.
Final products are high purity of methyl esters (99.8%) and glycerol (96.4%).
Production of methyl esters from Pithecellobium dulce seed oil (PDSO) is carried out through transesterification process.
Insight was provided into the high-temperature kinetic pathways of methyl esters in flame environments.
FTIR results demonstrated a strong peak at 1742 cm−1, showing carbonyl groups (C=O) of methyl esters.
Glycerol is normally generated at the rate of 1 mol for every 3 mol of methyl esters synthesized [4].
These two peaks confirmed the presence of methyl esters and its integration areas confirms the conversion on each sample.
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