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This polymer is made photocrosslinkable by the incorporation of methacrylate groups.
The use of acrylate groups for polymerization, instead of methacrylate groups, also yields low Tg and thus high conductivity.
A significant thermosensitivity was observed only when the molar amount of NIPAAM incorporated in the network was at least eight times higher that of methacrylate groups on pullulan.
Then, MIca was dispersed uniformly in HAMA solution and covalently introduced into HAMA by the reaction of methacrylate groups between HAMA and MIca during the formation process of hydrogel.
When the equilibrium water content of the dextran phase was 70%, the final conversion of methacrylate groups was around 90% and was reached within one hour, even at relatively low concentrations of KPS and TEMED.
Photoacoustic Fourier transform infrared spectroscopy (PA-FTIR) and X-ray photoelectron spectroscopy (XPS) confirm the formation of Si O Si, P O P and Si O P linkages and simultaneous polymerization of methacrylate groups leading to a dense networked structure.
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Clay Polymer interactions were modulated by varying the surface treatment of clays: a physical interface was formed with the compatible surfactant showing aromatic groups (MMT-benz) and a chemical interface was created after reaction of methacrylate group (MMT-MHAB) with the styrene monomer.
These hydrogels are photocross-linkable via incorporation of methacrylate group.
Cross-linking of the methacylate groups postassembly of the nanoparticles further reduced the bilayer permeability, thus leading to another increase of the particle stability in physiological media, exclusively at an intermediate degree of substitution for methacrylate groups to the polymer.
Here we explore a method to overcome this deficiency by incorporating methacrylate functionalized carboxymethyl cellulose (MetCMC) into the CNF system followed by UV irradiation leading to crosslinking of the methacrylate groups of MetCMC.
The DS was determined from integral ratios of peaks of the methacrylate groups at 6.2 ppm compared to peak corresponding to methyl groups in heparin at 2.05 ppm.
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