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In all polyesters, the formation of ether groups was observed.
These results demonstrate the consistent growth of cluster size with pyrolysis temperature, and examine for the first time the distribution of ether groups and defects within the cluster.
In fact, the presence of ether groups improves the polymer solubility in polar solvents and, consequently, the membrane and MEA processability.
These results highlight the contribution of defects to the structure and show localization of ether groups toward the periphery of the clusters.
Methacrylates and acrylates containing different number and types of ether groups were selected to determine the effects of ether group concentration and structure on oxygen inhibition.
Model poly tetramethylene oxide) and poly(propylene glycol) system were evaluated to determine the effect of ether groups on polymerization kinetics in air.
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A proposed mechanism of dipole cationic binding of ether group of PEG to Fe3O4 surface and hydration process of PEG for aqueous dispersibility.
(1) The CO formation can be mainly attributed to the cleavage of ether group, the removal of anhydrides, oxygen free radicals reaction, and cleavage of carbonyl groups.
Esterification of 36, followed by protection of the amino group afforded 37. Methylation of 37 with iodomethane and then reduction of ether group with NaBH4 gave 38.
And the proposed mechanism of dipole cationic binding of ether group of PEG to SPION surface and hydration process of PEG for aqueous dispersibility is illustrated in Figure S5 (see Additional file 1).
CO formation at low temperatures was related with the cleavage of ether group (Reaction 2), and this reaction occurred at a relative wide temperature range from 300 to 500 °C (Liu et al. 2014a, b).
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