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An alternative approach to the problem of surface catalysis involves the consideration of electronic factors in catalyst and reactants.
They also tend to indicate that it must be the presence of electronic factors in the monolayer levels of the adsorbed cobalt phthalocyanines which are completely different from those present in the tri-dimensional arrays of the active part of the thicker adsorbed or electropolymerized complex deposits.
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The intrinsic electrocatalytic activity is mainly due to electronic factors, as result of the synergism between Ru and Ce oxides.
Evidence for electronic factors in the nucleophilic cyclization of ambident amides to oxocarbenium ions.
Analysis of the electronic factors of representatives from a broad series of MN2S2 complexes is referenced to electrochemical redox events as well as the vibrational spectroscopy of diatomic ligand reporters.
The mass activity of PtRu/TiO2 for methanol oxidation was determined by the interplay of the surface electronic factors at the metal solution-interface and the value of the oxophilicity of the nanoparticles was increased by decreasing the particle size.
Whereas O2 chemisorption is barrierless, adsorption of NO is a complex function of geometric and electronic factors.
Structural diversity of such type systems is demonstrated, and the influence of steric and electronic factors on their stability is considered.
The effects of hydrophobic and electronic factors in the 2,2-disubstituted sacrificial amine source and the pyridoxamine catalyst on turnover frequency and turnover number are explored.
Most N1-substituents were taken from bacteriostatic sulfonamide structures and presented a more complex behavior, possibly due to a conjugation of steric and electronic factors.
Thus, highly selective polymerization of ethylene is possible in a mixture of ethylene/propylene probably due to both steric and electronic factors of these complexes and this substrate selectivity is also similar to zeolite-based catalysts [26].
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