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The Cr VI) sorption was observed irreversible due to strong bonding of HCrO4 − and the presence of active sites.
These polymers display a previously observed irreversible high temperature exothermic transition that is attributed to a solid-state reorganization to intermolecularly hydrogen bonded amide pairs.
The observed irreversible response has been attributed to the effective blocking of water molecules at the assembly of 1 and 2 on the long chain alkanethiol-coated electrodes in the presence of weakly hydrated PF6- ions.
In a previous study, we have observed irreversible tidal volume (and expiratory flow rate) depression after inhalation of an aerosolized nanofilm product which induced alveolar collapse.
TPR domains are known to self-associate [ 20] and we have in the present study observed irreversible aggregation and precipitation of Tah1 on prolonged storage and during handling of the protein.
Moreover, the increased negative ellipticity, with the 212 216 nm minimum, was maintained when RIα 92 381) was cooled down to 25°C (Figure 2A), indicating that the N-terminal D/D domain and dimerization of full length RIα did not contribute to the observed irreversible thermal transition.
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Clinically, one can observe irreversible skin hyperpigmentation, ephelides, lentigines, abnormal elastic fibers, telangiectasias, sebaceous gland hyperplasia, and rhytids.
After application of a force of 4,800 N (100 h) and then 9,200 N (64 h), we did not observe irreversible destruction of the implants.
Some processes, Carnot observed, are irreversible.
The kinetic isotope effect is observed in irreversible or unidirectional reactions, such as evaporation, diffusion, and biologically mediated reactions.
On a bare HOPGE, they observed an irreversible anodic peak at 250 ± 30 mV against a normal hydrogen electrode, while at the DNA-modified HOPGE, a quasi-reversible redox couple was observed at 20 ± 10 mV.
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