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Higher Fe concentrations would give rise to a larger net rate of oxidation.
The oxidation rate and Fe(II) resupply from the bulk soil could partially account for this, because this would impact the net rate of oxidation and the distribution of iron species in the soil.
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At potentials < −0.4 VSCE the presence of Fe2+(aq) in solution somewhat suppresses the dissolution of FeII, thus reducing the net rate of anodic oxidation, while at potentials > −0.4 VSCE the presence of Fe2+(aq) at 0.1 mM can substantially increase the rate of formation of γ-FeOOH on the carbon steel surface via oxidation of Fe2+(aq).
Indeed, it has been suggested that considerable metal promiscuity may be rather common for dioxygenases that only change the metal ion's oxidation state by one charge during catalysis, as the net rate of the metal ion oxidation by O2 and the subsequent reduction by the substrate may compensate one another [124].
It has been argued that a strong coupling of metal ion oxidation and subsequent reduction by the substrate may compensate for one another, so that the net rate of these two steps could be similar for metal ions with distinct redox potentials [123].
Net rate of production of species i by chemical reaction.
The presence of H2 or CO reduced the net rate of carbon deposition and increased the net rate of carbon removal by diffusion through the Co, respectively.
The measured concentration gradients of hydrogen was used to estimate the net rate of radiolysis.
This is done by complex balancing or by equating the net rate of inflow into the complex to the net rate of outflow from it.
Their offensive rating in the fourth quarter was 109.2, giving them a net rating of 10.2.
Species flux-balance calculations were used to obtain net rates of reaction for the species.
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