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In trans─trans racemic pBrS─pBrS diads, neighboring side chains are placed on opposite sides of the copolymer backbone in position for their p-Brs to strongly interact with the silicon wafer surfaces.
A plan to transform downtown Jamaica, Queens, into a vibrant "airport village" while preserving the quiet, low-scale character of neighboring side streets cleared an important City Council committee yesterday, all but ensuring final approval next month for the single largest rezoning of the Bloomberg administration.
It is therefore not surprising that the mutant His115 side chain exhibits an energetically favorable interaction with at least one neighboring side chain (Fig. 2d).
The lack of hydrogen bonding with neighboring side chains increases the mobility of this residue.
The mutations induce rotations of neighboring side chains but otherwise have minimal impact on the protein structure.
This was probably caused by the combined weight of the two adjacent buildings resulting in a greater settlement on the neighboring side.
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Inspection of crystal structure overlays reveals very minor perturbations to the residues and neighboring side-chains highlighting the sensitivity of F NMR for identifying small conformational effects.
The top panels show a close-up of the proton-binding sites, D407 and D408, along with neighboring side-chains, including K940 in the foreground and R971 in the background.
However, in metallo-proteins, an internal metal ion often is coordinated by charged residues and hence the overall charge on the molecule is influenced by the neighboring side-chain groups which give the protein a varying net charge depending on the pH of the solute, which influences its binding and elution in an ion exchange column [ 22].
Incisions 1 to 2 cm long, depending on nerve thickness, of the epineurium and partial perineurium were made at the neighboring sides (Fig. 1a).
Infrared spectra showed that in the Ca2+ complex of model comprising the binding Asp residues of LA, the cation is coordinated to the COO− groups of all three Asps, while in the complex of model comprising nonbinding Asp residues of LA, the two neighboring Asp side chains form a bridged Ca2+-binding system.
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