Sentence examples for neighboring group from inspiring English sources

Carboxyl groups and unsaturated centers usually react independently; however, when in close proximity, both may react through neighboring group participation.

Glycosylation with the pseudosugar involved stereoselective neighboring group participation of p-anisyl group and gave the nucleoside derivative in 94% yield.

Ring opening of methylene-interrupted di-epoxides leads to the formation of 5- and 6-membered ring ethers through neighboring group participation [26].

Computational studies have served to provide nuance and clarity on several key aspects, including the role (and consequences) of neighboring group participation in cation generation and stabilization.

Invoking neighboring group effects in the COR is particularly appealing as it simultaneously lowers the transition state energy and advances the reaction coordinate of a productive COR.

However, on the basis of an inability to identify a catalytic nucleophile in the complex with α-glucosyl-1,3-isofagomine, a neighboring group participation mechanism for GH99 was suggested that proceeded through a 1,2-anhydro sugar [ 48 ].

If the group beneficial trait becomes common in one group, the high payoff causes individuals in neighboring groups to adopt the group beneficial variant, which can tip the neighbors into the basin of attraction of the group beneficial trait.

The males never strayed far from home, and the females dispersed after puberty to neighboring groups.

So, too, young males form raiding parties to murder chimpanzees from neighboring groups, but they lack the concept of murder.

In chimpanzee societies, males stay where they are born and females disperse at puberty to neighboring groups, thus avoiding incest.

Bonobos engage in fellatio; there is frequent male-male and female-female sexuality; and, perhaps most remarkably, encounters with neighboring groups lead not to violence but to intercourse.