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Sato, S., Sakamoto, T., Miyazawa, E. & Kikugawa, Y. One-pot reductive amination of aldehydes and ketones with alpha-picoline-borane in methanol, in water, and in neat conditions.
Base-free catalytic acceptorless dehydrogenative homo-coupling of alcohols to esters under neat conditions was investigated using a combined organometallic synthesis and kinetic modelling approach.
The disclosed procedure is rapid and the convenient synthesis of benzimidazole amine hybrids from easily available substituted cyclic, acyclic amines, and benzimidazole under neat conditions in the presence of catalyst tris(2,2-bipyridine)ruthenium II) chloride.
We have discovered that, in sharp contrast to all common reaction protocols using highly reactive organometallics such as organolithium compounds, the Pd-catalysed cross-coupling of arylbromides and alkyl- or aryllithium reagents under neat conditions proceeds exceptionally fast and is selective.
Using chlorobenzene as the solvent the polymer had an Mn of 350 000 and PDI of 1.21, where as under neat conditions the Mn was 255 000 with PDI of 1.21.
The synthesized PG with a high phosphorous content of 1.61 at% is found to exhibit efficient metal-free heterogeneous catalytic activity for aerobic oxidative coupling of amines catalysts under mild and neat conditions using molecular oxygen as the oxidant.
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Metropolis had always been in neat, orderly condition.
Deprotection of tosyl group was achieved with TFA (catalyst and solvent) at 140 °C to obtain 4-hydroxytetrahydropyrans and further reaction of 4-hydroxytetrahydropyrans with cinnamoyl chloride afforded 4-cinnamate tetrahydropyrans under neat condition.
"Its engines were installed," says Baker, "and it was in a pretty neat condition to get it over to the vehicle assembly building fast and launch it".
Residents of Central Campus Apartments are responsible for maintaining the areas adjacent to their apartments in a neat and orderly condition.
It is also found that under the neat methanol operating condition, water distribution across the membrane electrode assembly is greatly influenced by the membrane thickness, the cathode design, the operating temperature, and the ambient relative humidity.
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