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Basu et al. (2006) verified that Pseudomonas putida CSV86 is able to degrade preferentially naphthalene over glucose.
Shape-selective isopropylation of naphthalene over a hydrogen-mordenite (HM) catalyst is an effective route for the production of 2,6-diisopropylnaphthalene (2,6-DIPN).
The L H equation, giving an adequate fit to the experimental data with physically meaningful parameters, suggested a competitive adsorption between hydrogen and naphthalene over the presulphided NiMo catalyst and a non-competitive adsorption between these two reactants over the prereduced Ni and Ru/Al2O3 catalysts.
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In order to understand such a differentiation in the formation of the two di- tert-butyl)naphthalenes over the HY zeolites, computational analysis of both energies andi- tert-butylmensions of these di- tert-butyld of the monaphthalenescovererpartheHYs been performed, using quantum mechanics (AM1 and PM3) and molecular mechanics (MM+) methods.
Figure 5 also exhibits the benzene and naphthalene yields over the three catalysts.
The airflow patterns around an array of in-line truncated boards and the sublimation process of thin naphthalene layers over the in-line boards have been simulated numerically.
Open image in new window Fig. 5 The methane conversions, aromatic yields, benzene yields, and naphthalene yields over Mo-IM-5-C (filled squares), Mo-IM-5-S (filled circles), and Mo-IM-5-M (filled triangles) catalysts.
A kinetic study of the liquid phase naphthalene hydrogenation over a commercial and sulphided NiMo/γ-Al2O3 was performed using experimental data obtained in a Robinson Mahoney reactor at 523 583 K and 2.0 4.0 MPa.
A further study at a reaction temperature of 473 K showed that naphthalene hydrogenation over these noble metal catalysts can proceed even in the presence of benzothiophene at a concentration of 4200 ppm.
Differences in compound equilibrium between silicone and the atmosphere could explain naphthalene concentrations over time, and it is known that naphthalene is difficult to interpret with work-related exposure due to confounders such as cigarette smoking.
DFT calculation confirmed that the two molecules were highly twisted and the dihedral angles between pyrene backbone and naphthalene unit were over 80°, being attributed to the steric hindrance of ortho-methyl group and the substitution position of pyrene itself.
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