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X-HRTEM studies revealed a nanometric grain size for all types of samples.
Nanometric grain size and large grain boundary could enhance the rapid recovery time and the Δ|Z| value due to the adsorption of the oxygen on the surface.
AlCrN and AlCrN/TiSiN response similarities result from the low influence played by the stratification as compared to the nanostructure of the polycrystalline sublayers (nanometric grain size).
It is observed that increasing the duty cycle from 30% up to 70% (for peak Vbias = −100 V and 100 kHz) increases the intensity of the rutile (110) as well the nanometric grain size of the film deposited.
Based on an analysis of the Raman spectra, these results are believed to result from the extended meta-stability of the cubic phase to reduced yttria levels at nanometric grain sizes.
In the current study, the best anticorrosive performances were observed for coatings containing 7.4 to 13 wt.% Co, presenting nanometric grain size and one predominant crystalline phase (γ-Zn21Co5).
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Finally, from the AFM analyses reported in Fig. 1, statistical data on the radius, area and volume of the Au nanometric grains forming the film can be obtained.
From such analyses, the Au film, in all the samples, results to be formed by spherical nanometric grains of increasing mean size [26].
In fact, the AFM analyses in connection with transmission electron microscopy analyses allow to conclude that the Au film is formed by three-dimensional nanometric grains that grows as "normal grains" for thickness in the 0.33 nm.
Blue green luminescent carbon nanodots entrapped in silica matrix were produced by the pyrolysis of methyl groups well dispersed on the edges of nanometric grains of silica (Aerosil® R974) previously cold sintered under high pressure.
These results arise because the unique microstructure (low content of long DWCNTs, nanometric matrix grains and grain boundary cohesion) provides the appropriate scale of the reinforcement to make the material tough.
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