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The multiplicity features of integral catalytic reactors are studied numerically for the noble metal catalyzed oxidation of carbon monoxide with oxygen.
A new linear algebraic method that makes use of the Carleman linearization procedure is given for determining the local multiplicity features of chemical reaction systems.
A solid circulation model is used to investigate the steady-state multiplicity features of a fluidized bed reactor in which a single, first-order, exothermic reaction occurs.
A simple procedure is presented for predicting the multiplicity features of distributed-parameter systems described by a single two-point boundary-value problem.
The reaction dynamics and multiplicity features of CO oxidation on a Pt/SiO2 catalyst are studied via transient experiments combining Fourier transform infrared spectroscopy (FTIR) with temperature-programmed reaction (TPR) and with concentration-programmed reaction (CPR).
The steady state multiplicity features of porous catalytic pellets, the temperature of which is uniform but different from that of the surrounding, are determined for a zeroth-order reaction.
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The surprising dependence of the multiplicity features on the reaction order and pellet geometry could not have been predicted by a lumped model of the system.
Multiplicity features for a cylindrical pellet, according to direct calculation, are shown to be analogous to those of a spherical pellet.
Several of the multiplicity features are atypical of conventional isothermal CO oxidation behavior, such as a (T̂w CO/O2) multiplicity region (bifurcation map) having an extinction branch with a local maximum, which is indicative of a pitchfork singularity.
The generality of the observed multiplicity features, the observation of hot spots, and the rational model construct rules out a more complicated kinetic mechanism that would be necessary to explain the data.
Simulation studies reveal the hitherto unreported existence of multiple isolas and unusual multiplicity features, arising from isola evolution for some regions of reactor parameter space.
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CEO of Professional Science Editing for Scientists @ prosciediting.com