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15N detection is beneficial in cases where carbon-detected methods suffer from multiple couplings to neighboring carbons, or in the study of proline-rich protein domains and paramagnetic metalloproteins.
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Even in the absence of stereochemical questions, regio- and chemoselectivity issues with heteroaryls in sp2 sp2 coupling are of tremendous interest because of the inherent reactivity differences across heteroaromatics, and the possibility of performing multiple couplings on polyhalogenated heteroaromatics3,23.
The crucial advantage of such multiple couplings is the fact that in principle spectroscopic and catalytic data are obtained from the same catalyst system for which identical reaction conditions are guaranteed.
17 For the di- and trifluorinated derivatives, multiple couplings of the alcohol hydrogen atom with the fluorine atoms were expected.
These growth-rate dependent couplings to cellular processes including transcription, translation and replication can influence the behaviour of synthetic circuits.
At lowest order, the only allowed interactions are derivative couplings to gauge fields and fermions.
In general, additional couplings to the constitutive equations (Equations 4– 6) exist, see (Fürthauer et al., 2012).
A structure-insensitive regime arises for redox partners coupled through dynamically averaged multiple-coupling pathways (in seven of the nine derivatives) where heme-edge coupling leads to the multiple-pathway regime.
Connect the Flex-Coupling to the pipe.
The increased SERS intensity was attributed to an increase in SERS multiple plasmon couplings among AgNWs (crossed and parallel gaps) and between the Au film and the AgNWs.
These results indicate that high-density AgNW films can lead to high light absorption by multiple plasmon couplings between neighboring AgNWs (crossed and parallel gaps) and between the Au film and the AgNW films.
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