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It has multiple catalytic centers located within the hollow cavity of a molecular cage.
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The mesoporosity of the oxide support favors the diffusion of reagents towards the catalytic centers.
Additionally, the achievements on the incorporation of catalytic centers based on transition metal complexes are summarized.
The second approach aims at synthesizing MOF materials having structural defects to generate active catalytic centers.
Further, the generation of isolated catalytic centers via grafting techniques is summarized.
ALDHs have multiple catalytic and non-catalytic functions in addition to their roles in aldehyde metabolism [19].
Complex enzymes with multiple catalytic activities are hypothesized to have evolved from more primitive precursors.
ORFs that include GH10 or GH11 xylanase modules commonly showed multiple catalytic modules.
Somatic ACE contains two catalytic centers in N- and C-terminal domains [10]), whereas a short testis-specific isoform expressed in germ cells contains an identical C-domain and only one catalytic center [11] [12].
The T-domain mainly functions as transportation of substrate and elongation of intermediate to catalytic centers.
The metal ions that were trapped by primeval RNA polymers could serve as catalytic centers.
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