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It showed correlation with miscellaneous descriptors: one constitutional (number of multiple-multiple carbon bonds MCB), one topological (PND), one geometric-electronic (FPSA-3), and two quantum-chemical (ELUMO and EN).
These are usually in regions surrounding electronegative atoms, above and below multiple carbon-carbon bonds and aromatic rings, and along the outer edges of strained carbon-carbon bonds.
Multiple divalent carbon bonds in saffron compounds confer its powerful radical scavenging, antioxidative and anti-tumor properties [ 10– 13].
We perform very long-time-scale, temperature accelerated molecular dynamics simulations of these topological defects and observe that they are able to flip polarity through concerted motion of multiple carbon atoms without breaking any covalent bonds; the simulations reveal the polarity flipping transition pathway.
In other homogeneous (or heterogeneous) catalyst systems in which the metal is likely to be in a relatively high oxidation state, such as molybdenum VI) or tungsten VI), metal-carbon multiple bonds may play an important role.
Rotations about carbon-carbon bonds interconvert two equally energetic chair forms.
In 1872, he co-discovered the Aldol reaction (a method of forming carbon-carbon bonds).
Two catalysts working in tandem form carbon-carbon bonds at a conventionally unreactive site.
Carbon-carbon bonds are strong, and stable.
Methylotrophic bacteria utilize reduced carbon substrates containing no carbon-carbon bonds as their sole source of carbon and energy [17].
Methylotrophy describes the ability of organisms to grow on reduced organic compounds without carbon-carbon bonds.
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