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As part of our investigations of An-ligand multiple bond chemistry,[ 14] we describe here the synthesis of a thorium carbene amide ketimide that features Th Ccarbene, Th Namide, and Th Nketimide bonds in one molecule.
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Heteronuclear multiple bond connectivity.
Fig. 5 Heteronuclear multiple bond correlation (HMBC) of DNPH-glucose.
NMR (heteronuclear multiple bond correlation through the double bond) confirms one GMA per chain terminus.
The reactions include simple bond cleavages but also complex reactions involving multiple bond cleavages and formation of new molecules.
Since then, his research group has addressed Fe-N2 chemistry, reactive metal-ligand multiple bonds, engineered metalloproteins, redox-active ligands, solar H2 production, and the mechanisms of organometallic transformations at base-metal complexes.
The table includes examples of molecules that have multiple bonds.
Two years later he discovered that unsaturated organic compounds contain multiple bonds.
The first, already mentioned, is the presence of multiple bonds.
Under certain bonding conditions, adjacent atoms will form multiple bonds with each other.
Rule C follows Weininger et al. and reduces the probability of bond closures involving multiple bonds.
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