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These parameters suggest that the Th Nketimide interaction may be stronger than the Th Namide interaction,[ 11] and may feature some multiple bond character.
An additional manifestation of the increased P=C multiple bond character in 6 is the fact that the PHC(O NH core of the molecule is largely planar (deviation from planarity 0.0876 Å).
A comparison of structural metrics between the anion and the neutral parent complex showed a significant shortening of the P=C bond (1.791 3) Å; c.f. 1.878(3) in 5, Δ dP=C=0.09 Å) indicative of a greater degree of multiple bond character.
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While this bond shortening agrees with an increased bond order, it is quite small when compared to carborane anions with substantial exo-multiple bond character.
In particular, the bond distances are consistent with a significant degree of Me2N=C and B=N multiple-bond character.
The experimental P1 P2 bond length of 2.148 5) Å is consistent with partial multiple P P bond character and is significantly shorter than that in 2 (2.2208(11) Å).
Heteronuclear multiple bond connectivity.
The increase in the Mo = S bond length shows the loss of the double bond character.
The C8 C9 and C11-C12 single single bond character with bond length of 1.45 Å.
The C7-O16 borderrder value is 1.968, which depicts the double bond character, while the C18-C20 and N4-C5 bond order values are approximately unity, which show the single bond character.
This fact can be attributed to restricted rotation around the C6 N bond due to resonance that gives this bond some double bond character [44].
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