Exact(1)
Another control experiment lacking H2O2 demonstrated much slower reaction kinetics, probably because horseradish peroxidase was able to convert molecular oxygen into free radical species at a much slower rate.
Similar(59)
In fact, the rate of reaction 2 is 2-fold faster than the rate of reaction 3, yet the span of reaction 2 is 2-fold smaller than the span of reaction 3. Similarly, reaction 2 appears much slower than reaction 4.
We say that reaction r1 is much slower than reaction r 2, v r 1 t ≪ v r 2 t if max t v r 1 t < k · max t v r 2 t, where k=10-2.
Water-soluble disulfides undergo further, although much slower, oxidation reactions to form higher oxidation products.
Receptor movement is neglected as diffusivity along the cell surface, D ~ 0.01 μm/s [ 62] is much slower than reactions at the cell surface; the Damköhler number is Da = koff·Ltip/D = 160.
In contrast, we could not obtain accurate calculation of rate constants for the SM reaction due to the much slower Exo III reaction.
The physicochemical properties of phosgene also preclude any spontaneous hydrolysis within this microenvironment because the reaction of phosgene with water is much slower than the reaction with the more nucleophilic chemical moieties –NH2, –OH, and –SH.
The effect of dissolution and precipitation of minerals other than calcium carbonate (such as silicates and aluminosilicates) was assumed to be negligible during the relatively short time frame of the experiment on the basis that the reaction rates of these minerals are much slower than calcite reaction rates [44].
Fenton-like reaction with the constant rate of 0.01 0.02 M−1 s−1 is much slower than Fenton reaction with the constant rate of 76 moreover moreover HO 2 · is less reactive than OH·; thus, Fenton is the dominant reaction in production of the radicals (Anotai et al. 2006; Sun et al. 2007; Ramirez et al. 2009).
13 The dehydrogenation reaction could alternatively be carried out at a much slower rate by reaction with excess MnO2 in dichloromethane for three days at 28 °C.
While this lateral component of etching is much slower than the reaction occurring directly at the regions of Si covered by the Au catalyst, thus conferring a high degree of anisotropy to the MCEE process, it will nonetheless impose a limit to the maximum achievable aspect ratio.
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