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The SPI membranes exhibited better permselectivity than Nafion 115 membrane due to their much lower methanol permeability.
All the PFSPI membranes displayed better permselectivity as compared with Nafion 115, which is attributed to their much lower methanol permeability.
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The CSPAEK80-20% system, CSPAEK membrane with 80% sulfonation and 20% cross-linking degree, exhibited a comparable proton conductivity to Nafion 117 but much lower low methanol permeability – about a half of that of Nafion 117, suggesting that it is a promising candidate as a polymer proton exchange membrane for fuel cells.
All other increases in volatile emission rates were much lower than that of methanol, although most of them increased several-fold relative to unattacked plants (including volatile wound compounds and monoterpenes).
The level of AOX1 mRNA, encoding the alcohol oxidase enzyme and therefore indicating the induction of methanol as well as an active methanol metabolism, was much lower than the level of procollagen II mRNA.
The methanol diffusion coefficients of membranes are much lower than that of Nafion (2×10−6 cm2/s).
The proton conductivity of the membrane with IEC of 0.9 mmol/g was 1.14 × 10−2 S/cm and its methanol permeability coefficient was 5.46 × 10−7 cmuch, much lower than that of Nafion-117.
As expected, the methanol permeability of the optimized multi-layer membrane was much lower, however, the proton conductivity of the membrane was higher than that of Nafion 115.
Assuming the Earth's ice-free land area (133.8×10 m) to emit methanol at this average rate year-round, which is an overestimation due to off-season fluxes being typically much lower than the growing season data compiled in this study (Bamberger et al., 2014), extrapolates to a global net land methanol flux of 135 Tgy−135
Moreover, the methanol permeability of SPAEK-100 membrane was 3.95 × 10−7 cm2/s, which was much lower than 23.80 × 10−7 cm2/s of Nafion 117.
The methanol permeability coefficient of C-SPAEKS-80 membrane was 9.15 × 10−7 cm2 s−1 at 20 °C, much lower than that of Nafion 117 membrane (22.9 × 10−7 cm2 s−10−7
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