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Temperature is sensed using 4.6 μA, 11.5 bit temperature to digital converter TDC with resolution of 0.1 °C in 100 ms conversion time.
For the conditions studied (λ = 4 6, Tin = 218 257 °C and residence time ∼5 ms), conversion of hydrogen and carbon monoxide were diffusion limited after ignition, while methane never ignited and was kinetically controlled.
EPR spectra were recorded under nonsaturating conditions using a 0.2 mW microwave power, a 100 kHz modulation frequency, a 1 mT modulation amplitude, and a 21 ms conversion time and time constant.
All measurements were carried out with 0.2 mW microwave power (MWP), 100 kHz modulation frequency, 0.25 mT modulation amplitude (MA), 41 ms conversion time and 41 ms time constant.
EPR spectra were recorded using 2 mW microwave power (MWP), 100 kHz modulation frequency (MF), 0.5 mT modulation amplitude (MA), 41 ms conversion time (CT), 41 ms time constant (TC) and 1024 points.
ESR settings were as follows: magnetic field center 3,386 G, sweep 9 G, microwave frequency 9.51 GHz, microwave power 21.9 mW, modulation frequency 86 kHz, modulation amplitude 2.6 G, modulation phase 359°, time constant 41 ms, conversion time 10.2 ms, and sweep time 5.2 s.
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At very short contact times in the range of 60 400 ms, conversions up to 70% have been determined.
To monitor the velocity of the reaction (k cat) during 200 s at 40 °C and to identify substrate concentrations associated with half-maximal velocity (K M), conversion of NADPH (0.4 mM) to NADP was recorded by a photometer (340 nm) in the presence of 0.05 to 0.4 mM substrate (progesterone, 2-cyclohexen-1-one, or methyl vinyl ketone).
The striking resemblance of the spectral shape of H135A, H34A, and H221A compared to that of wild-type SRI suggests that these residues are involved in neither the intramolecular proton transfer nor any alterations in the hydrogen bonding network in the SRI-to-M conversion.
Insertion reaction mechanism: M O x + yL i + + y e - ↔ L i y M O x (1) Li-alloy reaction mechanism: M x O y + 2yL i + + 2y e - → xM + yL i 2 O ( e. g., Sn O 2 ) (2) M + zL i + + ze - ↔ L i z M (3) Conversion reaction mechanism: M x O y + 2yL i + + 2y e - ↔ xM + yL i 2 O (4).
When the residence time was longer than 100 ms, CH4 conversion was above 98%.
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