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Thus, the deposition of metal and carbon takes place preferentially at the pore entrance, which causes pore mouth plugging.
The results showed that pore mouth plugs completely blocking pore necks are indeed formed, significantly retarding the hydration process taking place behind them.
The role of pore mouth plugging, in particular, was studied and it was found that it had a significant effect on the deactivation behavior.
The effect of the pore mouth plugging was also investigated and it was found that this phenomenon had a pronounced effect on the deactivation behavior of the catalyst.
The yield of intermediate is shown to theoretically follow a rising-falling-rising pattern when the deactivation is pore mouth plugging dominated.
The formation of pore mouth plugs appeared to be the consequence of the spinning top shape of pores as well as of other structural features such as the size distribution of microcrystallites around the pore walls.
The characterization results show that the silica-alumina NiMo catalysts are more sensitive to metal deposition than carbon deposition because of their porous structure which provokes pore mouth plugging and the decrease of the NiMoS active sulfide phase.
This behaviour is due to mouth plugging initially sealing-off low yield small diameter pores, with a subsequently falling yield as the constricted mouths of larger pores introduce additional diffusional resistances, and a final improvement in yield as deactivation becomes so complete that the conversion achieved approaches zero.
You can't talk with your mouth plugged up.
It was revealed that a pore structure in which the pore diameter is enlarged increases hydrodemetallization activity and will be very effective for improving metal resistance because pore-mouth plugging can be curtailed.
Close your mouth and plug your nostrils.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com