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Co/Al2O3 is the most selective catalyst for hydrogen production from GSR reaction; H2 selectivity reached 70%% over this catalyst at 800 °C.
Cu/SiO2 was the most selective catalyst yielding 100% PHE.
Zeolite HZSM-5 was the most selective catalyst, yielding 96% STY.
The most selective catalyst for methacrolein formation at low temperatures (<496 °C) is Cu2.5H[PMo12O40]2, where both Cu II) reduction and acid sites play a role.
Pt CeO2 is not only the most active but also the most selective catalyst, reaching near 100% CO2 at low temperature (ca. 100 °C).
From Fig. 10, Co/Al is the most selective catalyst to methane production at lower reaction temperature, while, as the temperature increase the selectivity to methane decrease to reach the lower value 10.15 % at 800 °C.
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Feng et al. [15] investigated the effect of various supports (Al2O3, TiO2, and ZrO2) on Cu/ZnO/MOx catalysts and found that the support material can influence the metal particle size and the reaction routes, with TiO2 and Al2O3 yielding the most selective catalysts for propanediols production in the vapor phase glycerol hydrogenolysis reaction.
Ruthenium enriches on the surface and since Ru is the most selective FTS catalyst toward higher molecular weight hydrocarbons, enhances the selectivity of unpromoted Co/CNTs toward higher molecular weight hydrocarbons.
The most selective NiVSb catalyst was the most easily reduced that was interpreted on the assumption of reaction redox mechanism.
Ruthenium enriches on the surface and since Ru is the most selective FTS catalysts towards higher molecular weight hydrocarbons, enhances the selectivity of unpromoted Co/CNTs toward higher molecular weight hydrocarbons.
The most active and selective catalyst was BaCO3 deposited on Au-electrode (anode).
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