Exact(29)
The isatinic hydrazone uses its lactim form in most complexes.
The results indicate that most complexes have an elongated X-H bond with a red-shift stretching frequency of 78-366 cm-1.
Most complexes showed a broad band in the range 3463-3203 cm-1 due to ν(OH) of the associated water or ethanol molecules.
Electron density transfer (EDT) from water to 2TX for the most complexes is positive but the charge is transferred from 2TX to water in the complex IV.
From the initial distribution of ions, fragmentation proceeds along the lowest energy pathway, which corresponds to sequential water loss for most complexes.
(iii) In most complexes, the band located at 1706 cm-1 due to ν(C=O) of the free ligand disappeared indicating the participation of the lactim- form in the chelation.
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