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The morphology of copper deposits was studied using scanning electron microscope (SEM).
However, in presence of saccharin, the kinetics and morphology of copper coating remain unchanged.
The influence of plating mode, chloride and thiourea (TU) on morphology of copper deposits has been studied.
The morphology of copper coating obtained with thiourea leads to a smooth and bright deposit whereas it is only slightly modified by saccharin.
That strongly suggests that activity is defined by a good contact between Cu0 and ZnO, whereas the selectivity depends on the morphology of copper nanoparticles.
Examinations presented in this work focus on studies of laser induced changes in surface morphology of the prepared samples, as well as on the surface morphology of copper layers deposited on these samples.
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The obtained morphologies of copper deposits are discussed in terms of the effect of hydrogen evolution on the hydrodynamic conditions in the plating solution.
The differences in the morphologies of copper foils pre-annealed under varying conditions can lead to substantially different adlayer number densities.
Morphologies of copper deposits obtained at overpotentials belonging to the plateau of the limiting diffusion current density and at higher overpotentials were examined by the scanning electron microscopy (SEM) technique.
Then, the volumes of the evolved hydrogen (calculated as the average current efficiencies of hydrogen evolution) and the morphologies of copper deposits, characterized by the SEM technique, obtained for the same ratio of CuSO4/H2SO4 were mutually compared and discussed in terms of the relative concentrations of hydrogen ions (H+) as a function of the H2SO4 concentration.
Figure 3d, e, f, g shows the morphologies of copper nanoparticles sintered with various laser power levels at a fixed scanning speed.
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