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What is noteworthy is that, compared with dip-coating, spray-coating method can prepare more uniform catalyst on substrate, resulting in more CNCs with high purity.
HNO3 treatment produces more active acidic surface groups such as carboxyl and lactone, resulting in a more uniform catalyst dispersion and higher catalytic activity.
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In Case 2, the catalysts showed a more uniform distribution; the whole catalyst bed was fluidized, which could significantly improve catalyst utilization.
By developing a numerical code it was found that the velocity and pressure profiles on catalyst surface are much more uniform, reactant concentration on catalyst surface is very more homogeneous and the power density is higher than parallel and serpentine flow channels up to 56%and26%6% respectively.
Also, more uniform fuel distribution at catalyst layer and higher cell temperature is achieved with wire mesh current collectors.
The TEM results show that Pd particle size distribution in the Pd/ITO-CNTs catalyst is more uniform than that in Pd/CNTs, indicating that the ITO can promote the dispersion of Pd nanoparticles.
The FTS performances of catalysts were evaluated in a fixed-bed reactor at 280 °C, 1.5 MPa, 2000 h−1, and H2/CO molar ratio of 2. The characterization results indicated that the TEOS derived catalyst displayed a more uniform pore size distribution, easier reduction and higher capability for CO and H2 adsorption than the AcSS derived catalyst.
The reaction kinetics for rhenium-promoted Ag and unpromoted Ag catalysts suggest that the catalysts containing rhenium present a more uniform distribution of sites for oxygen adsorption than do unpromoted catalysts, thus enhancing the ethylene oxide selectivity.
Simulations also indicated that the rate at which the catalyst bed becomes more uniform from one pulse to the next is sensitive to reaction order: the desired uniformity is established for a second order adsorption after smaller amount of pulses than for a first order adsorption.
TEM confirmed this observation and revealed that this catalyst has well-dispersed, more uniform metal particles.
Longer milling durations produced finer catalyst particle sizes and more uniform dispersions, but yielded higher hydrogen desorption temperatures.
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