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By breaking the C‒C bond of the phenanthro[9,10-d]imidazole acceptor, we obtain the acceptor, 1,4,5-triphenyl-1H-imidazole, with a more twisted conformation.
Quantum chemical calculations indicated that protonation of the pyridyl units could narrow the band gap of PyVA, and X-ray crystallography revealed that PyVA molecules packed in a Z configuration in which the pyridyl units adopted a more twisted conformation with lone N-electron pairs stabilized by intra- and intermolecular CH···N and CH···π interactions.
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Due to its more twisted molecular conformation, PhDMe(DPP 2 shows more blue-shifted absorption bands, higher electron mobility, and better miscibility with the polymer donor poly 3-hexylthiophene) (poly 3-hexylthiopheneto P3HTPP)2.
This is a result of the quite larger space hindrance induced by 3,5-bis trifluoromethyl phenyl with two trifluoromethyl groups bonded at meta positions could make DMTCS-CC6 exhibit more twisted spatial conformation, leading more efficient solid state fluorescence and better structural transformability.
The first intermediate exhibited D-ring isomerization, whereas the second intermediate exhibited a more twisted chromophore conformation but a more relaxed protein environment.
Molecule 1.11b was subsequently found to have a significantly improved PCE of 6.4% ascribed to more efficient molecular packing and improved isotropic charge transport due to a more twisted molecular conformation caused by steric interactions with the methyl groups.
Furthermore, the dramatic blueshift observed for HS-136 bound to the deposits indicates a more twisted and rigid conformation of this dye than of the other LCOs.
Also, it was clarified that PI DAPT-6FDA) had a highly twisted conformation comPI DAPT-6FDADAT-6FDA) in thadground state, and a more twisted dihighly angle betwistedhe D and aconformationunits was inducomparedhe Ctostate, which led to the non-volatile memory characteristic.
That is infinitely more twisted and sad.
Who will escape?" Sounds like an even more twisted take on Suicide Squad.
These days, we live in an even more twisted world.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com