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In this situation, adsorbed on the solid surface polymer chains creating more stretched conformation with numerous loop and tail structures.
The more stretched conformation of polymer chains is, the weaker screening of surface groups should be observed.
A third more stretched conformation has been observed experimentally at mild acidic pH in the absence of Ca2+ (Illien et al., 2010).
PAA has a higher charge density at pH 7.4 than at pH 4.6 and, therefore, is forced into a more stretched conformation, yielding thinner layers.
The finding can be explained by a more stretched conformation of the longer hydrophilic chains, thus increasing the micellar size [ 53].
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As an instance, when the substrate thickness increases via crystallization temperature, the chains tend to gain more stretched conformations.
The two epimers revealed different conformations at the air/water interface resulting in a more or less tendency for a bent or a stretched conformation.
Different from the common polymer brushes with fixed tethering density, of which polymers are attached either chemically or physically on a substrate, the polymer brushes tethered on the single crystal are "smart" and partially release the highly stretched conformation by "telling" the crystalline blocks to provide more surface area via forming higher folded chain single crystals.
Our structural data analysis shows that the activated YfiB has an N-terminal portion that is largely altered, adopting a stretched conformation compared with the compact conformation of the apo YfiB.
The wrap-around conformation favors the decease of the surface energy of AuNP, and in contrast, the stretched conformation favors the increase of entropy.
The results suggested that the conformation of polyA's with varied length at the end of the aging step was neither the wrap-around state nor the stretched conformation.
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