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Similar to the coordination of Zn2+ in rKLK2 the catalytic His57 could constitute a more stable coordination sphere for the cation [145].
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In general, symmetrical coordination is more stable than asymmetrical coordination; however, there are two ways to define relative phase and the associated symmetries.
Additionally, international swimmers are able to maintain a higher energetic and biomechanical capacity than national swimmers [ 15] and high-speed swimmers have a higher and more stable stroke length and index of coordination than low-speed swimmers [ 36].
However, for the alkali metal cations, the second coordination sphere is not well-defined as the +1 charge on the cation is not high enough to polarize the water molecules in the primary solvation shell enough for them to form strong hydrogen bonds with those in the second coordination sphere, producing a more stable entity.
During MD simulation enol form is found to be more stable over its keto form due to their coordination with catalytic Nickel ion of Urease.
For the parameters used in [11], coordination at in-phase is more stable compared to anti-phase for frequencies comparable to those used in our VPI study (1 Hz to 3 Hz).
DFT calculations support this rationale as the additional coordination makes the gold carbene more stable.
In addition, IrIII is a more stable oxidation state than IrI with a higher coordination number (6 versus 4), which can provide extensive structural diversity from a wide range of ligands.
Although no coordination number or geometry is inherently more stable, most zinc-dependent proteins feature a resting state with a tetrahedral zinc center [in some cases, Zn II) is found in a five-coordinate trigonal bipyramidal geometry].
The P4VP has a more flexible chain that saturates the FeII center and results in stable coordination; FeIII/FeII redox reaction is therefore an obstacle.
This 0° visual phase relationship should be more stable for the human motor control system, at least for visually dominated coordination tasks.
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