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Furthermore, no induction period was observed by monitoring the cycloisomerization of 11 a to 12 a, b in CD2Cl2 at 0 23 °C.[ 25] Catalyst 7 c with a NTf2 ligand is a more reactive catalyst than 9.
Although the enantiomeric excess was only marginally better than that obtained with L2(AuCl) 2, phosphite gold complex L12(AuCl) was a significantly more reactive catalyst, leading to 2a in nearly quantitative yield in 12 h reaction time (vs. 24 h required with L2(AuCl) 2).
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When the more reactive nickel catalyst was employed instead of the palladium catalyst in the reaction, both dehalogenative and desulfonative homocouplings of haloaryl sulfonates occurred regardless of the type of the halogen used.
At this juncture we decided to examine the use of more reactive CoIII catalysts.
Heterogeneous base catalysts are generally more reactive than solid acid catalysts which require extreme operating condition for high conversion and biodiesel yield.
We have also found that complex 7 c with a borylphosphine ligand is catalyst more reactive than [((2-biphenyl) tBu2P Au(MeCN ]SbF6 (2 a) in a more challenging cycloisomerization reaction.
…new soluble organometallic catalysts, termed metallocene catalysts, have been developed that are much more reactive than conventional Ziegler-Natta catalysts.
More recently, new soluble organometallic catalysts, termed metallocene catalysts, have been developed that are much more reactive than conventional Ziegler-Natta catalysts.
This improvement was likely attributed to the formation of a more reactive Rh species on the catalyst surface.
Its tiny size makes it more reactive than traditional iron-oxide catalysts, allowing faster conversion of the propellants and greater speed or range for the missiles.
The soot collected after an oxidation catalyst (A-soot) is more reactive than the counterpart virgin soot obtained under the same engine operating modes but before the oxidation catalyst.
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