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In more ordered polymer chains, the Coulombic interchain coupling is weaker, which leads to narrowing exciton bandwidth.
The weaker spectral transformation of (6,4) nanotube band can be explained by more ordered polymer adsorption on this nanotube when polymer wraps tightly around the nanotube and restricts the access of water molecules to its surface.
In contrary to a more ordered polymer poly(di-n-hexylsilane), no clear thermochromic transition has been detected in PMPS film; however, the trans band intensity increases with temperature and with excitation wavelength, but it is absent when polymer is incorporated into nanopores of small diameter.
This is in agreement with DSC and NMR results: photo-nBA is less prone to water percolation because it is a more ordered polymer (Tg = −50.4 °C), while the addition of 10% MMA monomer to the poly-nBA chain decreases the order of the polyacrylate matrix (Tg = −42.6 °C).
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Mutations in α1-antitrypsin increase or decrease its tendency to form pathogenic ordered polymer chains.
Above the threshold, two main features can be observed: (i) the conjugation length of polymer chain segments reaches its maximum and (ii) polymer stacking in more ordered and larger crystalline domains influences strongly the material properties, namely enhances the exciton diffusion length.
The structure of polymers becomes more ordered, and the successive bonding of monomer molecules into polymeric chains can be seen.
At increasing concentrations of aqueous potassium bromide, the polymer structures became more ordered than those in low concentrations.
Polymer PBT possesses greater self-organization ability and thereby more ordered intermolecular packing in solid state.
As the polymer concentrations in aqueous solutions increase, the aggregated polymer exhibited more defined ordered structures than random structures observed at low polymer concentrations.
More orders followed.
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