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We recorded current transients after potential jumps from the open circuit potential to more noble potentials.
The increase of Rpf is mainly attributed to the thickening process of oxide film at more noble potentials.
Moreover, a third dissolution peak occurred at more noble potentials in mechanical alloys, but not in as-cast alloys.
The presence of l-proline leads to a great shift in the polarization curve and the deposition potential towards more noble potentials, indicating the catalytic effect of l-proline on the reduction of Ni II) ions.
The alloy with 13% phosphorus appears to show two separate regions of film formation: at low potentials, a thick, porous and less protective film is formed than at more noble potentials.
Indeed, the outer part of the passive layer on tested SS was found to behave like a conductor at potentials more active than −150 mV Ag/AgCl, and like an n-type semiconductor at more noble potentials.
Similar(48)
The cold sprayed coatings showed more noble corrosion potentials but higher corrosion current densities than those of the T6 6061 Al substrate.
The higher reaction rate was obtained for the system of quinone with a more noble redox potential.
The CrTiAlN coated Ti6Al4V, when tested in 3.5% NaCl aqueous solution, shows a markedly more noble corrosion potential in comparison with the uncoated Ti6Al4V substrate.
Electrochemical measurements showed a decrease of corrosion resistance in the samples nitrided during 20 h at 673 and 773 K. Conversely, the sample nitrided at 623 K presented a low corrosion current and more noble corrosion potential.
Compared with the bare and CLP treated substrates, the Ni P deposits showed more nobler corrosion potential and also lower corrosion current density.
More suggestions(15)
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