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As shown in the top view and cross-section SEM images, the amount of deposited graphene materials increases with more negative deposition potential.
It is suggested that more negative deposition potential produced larger deposition current and resulted in more graphene sheets deposited on the NFs.
The clusters were also larger at more negative deposition potentials and at higher solution pH.
This is because more negative deposition potential would produce stronger electric field and thereby larger deposition current.
This is in agreement with the cyclic voltammetry which clearly shows that Ge has the more negative deposition potential and is hence not yet in the mass limited transport regime.
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This results in a more negative electroless deposition potential and lower deposition rate.
These results indicate that the nucleation mechanism of Dy(0) changes from instantaneous nucleation to progressive nucleation when the applied overpotential becomes more negative than the deposition peak potential of Dy(0), as estimated from a voltammogram.
Cyclic voltammetry reveals that the more noble metal, Ni, deposits preferentially to Zn. Ni Zn co-deposition was achieved via deposition of Zn upon deposited Ni, at potentials more negative than that of Ni deposition, resulting in a Zn content always less than 50 at.%.
This was due to silver(I) ion complexation with thiourea, which shifted the silver deposition potential to more negative value and due to silver zinc alloy deposition, which occurred at potentials more positive than the potential to zinc deposition alone.
In titration experiments, metal is added to an unknown sample and the inorganic form of the metal (e.g., Fig 1A for inorganic Zn indicates that the deposition potential should be more negative than -1.1 V) is analyzed via deposition experiments for possible reaction at the Hg electrode.
However, Pt films grown by SLRR of Cu UPD show a larger potential window of differences of ∼26 mV over which the peak maximum potentials shift more negative with the number of deposition cycles.
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more negative evidence
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more uniform deposition
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more atmospheric deposition
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