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In all cases, water mobility differs from that observed on bulk molecules because even the more mobile water molecules contained in the lumens (diameters of about 10 and 70 μm) are more confined than they would be in the bulk, due to interactions with the cell wall surfaces.
This is attributed to the presence of more mobile water phase during the late injection of SC-CO2. 2.
Part of the (more mobile) water molecules is contained inside the vacant lumens, shown in Figure 12a.
The lorentzian-like line was assigned to more mobile water molecules located in the core of both large and small vessels, and also within the cell wall around the lumens, also observed in the relaxation measurements.
These results suggest that the more mobile water molecules are easily removed during the initial steps of the drying procedure and, at the end of the process, only water molecules contained within the cell wall around the lumens remain in the vessels.
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Other, looser reaction complexes may rely on tightly bound waters (as may be identified by crystallography of sufficient resolution) and/or more mobile waters to provide water molecules that are hydrogen-bonded to NTPs and ligands of metals.
Lipid and water formed the mobile phase, however, lipid molecules were always more mobile than water.
Unexpectedly, from the shape of the ESR signal it was noticed that of the NO radical of TEMPO in PPO membrane was more mobile than in water media.
These results indicate that for unsaturated flow conditions at higher matric potential heads (i.e., here >− 40 hPa), water in a restricted part of the fragment domain must be more mobile as compared to water in the sandy matrix domain.
This suggests the presence of two types of water within the polymer matrix; a less mobile phase of absorbed water that is interacting strongly with the polymer matrix and a more mobile phase of absorbed water residing within the cracks observed in the environmental scanning electron micrograph.
For this reason, T2 relaxation measurements are more appropriate for studying mobile water molecule dynamics.
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