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The higher temperature provides more heat, which can shake the membrane chains and molecules, thus leading to more free volume, which consequently reduces the methanol blocking effect.

Rolling creates more free volume, and deformation-induced residual stress distribution in a heavily rolled specimen relative to the as-cast specimen has been determined.

A polymer electrolyte with MBMI additive provided more free volume space, and the ionic conductivity of gel copolymer electrolytes was measured as a function of the salt concentration of lithium hexafluorophosphate (LiPF6).

Based on these investigations, one can conclude that the interaction between polymer matrix and nanotubes may disrupt the polymer chain packing thus enhancing gas diffusion due to introducing more free volume voids between the polymer chains and nanoscale defects on the polymer/nanofillers interface.

Besides, the intervention effects of HZIF-8 nanospheres on the SA chain packing also contribute to the enhancement of permeation flux and separation factor by rendering the membrane more free volume cavities and suitable free volume cavity size for ethanol/water separation.

Similar(55)

The increased temperature would produce more free volumes in polymer chains to facilitate the permeation of the compounds.

During the crosslinking reaction, the polymer chain is more and more enlarged, and therefore the free volume is reduced, which increases the viscosity [39] due to a reduced mobility of the molecules [40].

The EVA40consists of more plastic (crystalline) phase and hence the nanofillers find it more difficult to disperse and hence form relatively more agglomerations, whereas in high vinyl acetate grades, the amount of free volume is more and hence the fillers can disperse relatively easily.

However, PET and PEN fail badly and are found to diffuse much more slowly than inferred from free volume vs diffusion coefficient behavior in the other polymers.

The equilibrium water uptake showed strong composition-dependent, which suggested that hydrophilic groups rather than free volume were more significant in determining ultimate water sorption.

The accelerated aging is consistent with the notion of enhanced mobility near the film surface, which allows polymer near the surface to reach a lower free volume state more quickly than the bulk.

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