In the case of benzo[ b]thiophene, the byproduct did not impede isolation of the 2-arylated product as observed for benzo[ b]furan.[ 13a] The more pronounced difference in the polarity of the byproduct and desired product allowed a more facile purification as compared with the benzo[ b]furan series.
The loss of the diamond phase was believed to decrease hardness and weaken splat interfaces, which led to more facile delamination in HVOF coatings, as well as severe brittle wear and fracture in APS coatings.
The increase in activity can now be attributed to more facile catechol dissociation, as the free N=H groups are significantly better hydrogen-bond donors than the pyridine hydrogens in TPA.
In 1964, the results — which today impress me as more facile than felt — made him the first American to win the top prize at the Venice Biennale, and, at thirty-nine, the youngest artist.
In the absence of methanol the reduction of N2O on Pd is more facile than on Pt as shown by the approximately four times lower apparent activation energy and lower Tafel slope (Pt: 0.111 ± 0.019 V dec−1, Pd: 0.084 ± 0.007 V dec−1 at 295 K).
Be that as it may, today, a more facile definition might state a partisan as someone who is "a fervent, sometimes militant, supporter or proponent of a party, cause, faction, person, or idea".
More recently, elevated A1C has been proposed as a more facile method for diagnosing diabetes (2).
This water is strongly ligated in PHD2, and a D315E variant with a weaker interaction with this water molecule, showed more rapid kinetics with respect to oxygen, possibly as a result of more facile H2O release to allow oxygen binding.
Use of a sulfoxonium allows more facile preparation of the reagent using weaker bases as compared to sulfonium ylides.
Overall, scaffolds developed by pre-ribose glycation process are preferred, as the related crosslinking technique is more facile and robust to obtain functional scaffolds.
