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Indeed, as shown in Figure 5c, HB800 has a more disordered carbon structure than Fe800 and possibly has a higher proportion of nitrogen atoms at edge sites.
The Cu rich surface showed more disordered carbon as opposed to graphitic carbon on Cu deficient areas in which Cu concentration gradually decreased toward the interlayer.
The D2 peak appears as a right shoulder on the G peak, and in more disordered carbon it merges together with the G peak, causing a broad G + D2 peak around 1600 cm-1.
The attractive electrochemical performance of the PGM is attributed to its unique porous structure with large specific surface area and the presence of more disordered carbon atoms produced by the KOH activation.
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At a low temperature, active carbon species lack the mobility to form crystalline carbon, and a more disordered form of carbon is formed [24].
A negative shift in the peak values also confirms the doping of heteroatoms in the graphitic carbons of samples SK2 and SKC2 as compared to sample S2 and more disordered graphitic C structures in these.
However, the result of Raman spectroscopy showed that carbon atoms of graphene nanoplatelets became much more disordered, due to the destroyed carbon domains during the process of chemical drafting.
In other words, CNTs with less disordered carbon were more easily to survive during the fabrication process and be transferred in to the micro wire, which resulted in the improvement of crystallinity comparing with the milled CNTs in the Raman spectra.
The energy barriers for diffusion in this anisotropic structure are found to be smaller, and the diffusion coefficient larger, than in the more disordered but isotropic SiC-derived carbon, despite the larger pore volume of the latter.
This core is coated by a more disordered B-containing C material.
The Raman spectroscopy is more useful than FT-IR to determine the presence and features of graphite and disordered carbon, yet we found no information on iron carbide using the Raman in literature.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com